No - you'll need to make sure you've activated your card first.
To activate your card, log in and follow the easy step by step instructions. During activation you'll be able to add an additional card holder, view your new PIN, make a balance transfer and personalise your account settings. You can also tell us how you'd like to receive any credit limit increases in the future. If you prefer you can activate your card using our app or over the phone by calling on 0800 068 4499. Call charges may apply. You need to be 18 or over to use the app. T&Cs apply.